Cobalt borate catalyzed decomposition of organic hydroperoxides

C - Chemistry – Metallurgy – 07 – C

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260/637

C07C 31/12 (2006.01) C07C 29/132 (2006.01)

Patent

CA 1250598

COBALT BORATE CATALYZED DECOMPOSITION OF ORGANIC HYDROPEROXIDES (D#80,403-F) ABSTRACT OF THE INVENTION A method for decomposing organic hydroperoxides to their corresponding alcohols is described. A solution containing the organic hydroperoxides is contacted with cobalt borate or co- balt borate on titanium dioxide catalyst. The hydroperoxide is reduced to at least 0.2 wt.% of the effluent and often less than 0.09 wt.%. Cobalt borate has the added advantage of not leaching cobalt into the effluent unlike known cobalt oxide decomposition catalysts.

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