Composite adsorbents for purifying hydrocarbon streams

B - Operations – Transporting – 01 – J

Patent

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B01J 21/04 (2006.01) B01D 15/00 (2006.01) B01J 20/04 (2006.01) B01J 20/08 (2006.01) B01J 20/18 (2006.01) B01J 29/04 (2006.01) B01J 29/08 (2006.01) C07C 7/13 (2006.01) C10G 70/04 (2006.01) C10L 3/12 (2006.01)

Patent

CA 2364052

Applicant has developed an improved adsorbent useful in removing contaminants from various hydrocarbon streams. The adsorbent contains a zeolite, an alumina and a metal component. The metal component (M add) is present in an amount at least 10 mole % the stoichiometric amount of metal (M) (expressed as the oxide) needed to balance the negative charge of the zeolite lattice. In a specific application an adsorbent comprising zeolite X, alumina and sodium is used to purify an ethylene stream in order to remove CO2, H2S, methanol, and other S- and O- containing compounds.

Le demandeur a développé un adsorbant amélioré utile pour éliminer des contaminants de divers circuits d'hydrocarbures. Cet adsorbant contient une zéolite, une alumine et un composant métallique. Le composant métallique (M add) est présent en une quantité représentnant au moins 10 % en mole de la quantité stoechiométrique de métal (M) (exprimée en termes d'oxyde) nécessaire pour équilibrer la charge négative du réseau de la zéolite. Dans une application particulière, un adsorbant composé du zéolite X, d'alumine et de sodium est employé pour purifier un circuit d'éthylène en en éliminant CO2, H2S, le méthanol et d'autres composés contenant S ou 'O.

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