Composite membrane/electrode electrochemical cell and...

C - Chemistry – Metallurgy – 08 – J

Patent

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204/191, 117/88.

C08J 5/20 (2006.01) C08J 5/22 (2006.01) C25B 9/10 (2006.01)

Patent

CA 1208166

TITLE Composite Membrane/Electrode, Electrochemical Cell and Electrolysis Process ABSTRACT OF THE DISCLOSURE A composite membrane/electrode, a process for making same, an electrochemical cell and a process for electrolysis of alkali metal halides, especially sodium chloride, are disclosed. The composite membrane/ electrode consists of an ion-exchange membrane which is impermeable to hydraulic flow of liquid and which comprises at least two layers of perfluorinated ion- exchange polymer each having an equivalent weight up to about 1500. Adjacent layers of the membrane are in adherent contact with each other. A first layer is of a polymer with - SO3M functional groups and a second layer is of a polymer with - COOM functional groups, M being Na or K. An electrocatalyst is bonded to at least one exposed surface of the membrane with a fluorocarbon binder. A chloralkali cell and process with such a composite membrane/electrode operate at low voltage, high current efficiency and low power consumption.

401945

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