Composite structures of membranes that are selectively...

B - Operations – Transporting – 01 – D

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B01D 53/22 (2006.01) B01D 71/02 (2006.01) B01J 19/08 (2006.01) C01B 3/34 (2006.01) C01B 3/50 (2006.01)

Patent

CA 2438533

The invention relates to a composite structure consisting of a relatively long filtration bar comprising, from the outside, an ultra-thin layer (26) that is selectively permeable to hydrogen and made from palladium or silver alloy. Said layer is disposed on a permeable, rigid, refractory substrate consisting of a more or less solid body (30) that is covered with an intermediary thin layer (28) having a relatively smooth surface. The body (30) and the intermediary layer (28) are made respectively by sintering with fine and ultra-fine Inconel grains. A rigid metallic axial structure (32) is embedded in the body (30). Veinlets (31), which are made in the body (30) through the destruction of thermo-destructible wires during sintering, increase the permeability of the substrate. The invention is particularly applicable to hydrogen-producing combustible gas processors.

Une telle structure composite comprend un crayon de filtration relativement long comportant è partir de l'extérieur, une couche ultra-mince (26), sélectivement perméable à l'hydrogène, réalisée en alliage de palladium et d'argent, déposée sur un substrat réfractaire, rigide, perméable, constitué par un corps sensiblement plein (30), revêtu d'une couche mince intermédiaire (28), à surface relativement lisse. Le corps (30) et la couche intermédiaire (28) sont respectivement réalisés par frittage de grains d'Inconel fins et ultra-fins. Une armature axiale métallique rigide (32) est noyée dans le corps (30). Des veinules (31) réalisées dans le corps (30) par destruction de fils thermo-destructibles au cours du frittage, augmentent la perméabilité du substrat. L'invention s'applique notamment aux processeurs de gaz combustibles produisant de l'hydrogène.

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