Composition and method for preparing copolymers of polar and...

Details Composition and method for preparing copolymers of polar and... Composition and method for preparing copolymers of polar and...

C - Chemistry, Metallurgy

08

F

C08F 210/02 (2006.01) C08F 2/38 (2006.01) C08F 4/80 (2006.01) C08F 220/14 (2006.01) C08K 5/132 (2006.01) C08K 5/29 (2006.01) C08K 5/34 (2006.01) C08L 23/08 (2006.01)

Patent

CA 2620884

A polymerizable composition including a late transition metal complex, a non- polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.

On présente une composition polymérisable comportant un complexe de métal de transition tardive, une oléfine non polaire, une oléfine polaire et un capteur de radicaux libres. Cette composition est capable de former un polymère d'addition linéaire pour ainsi dire exempt de radicaux libres de la forme poly¬oléfine non polaire)-(oléfine polaire)| divulgue aussi une méthode de copolymérisation d'une oléfine non polaire avec une oléfine polaire, catalysée par un complexe de métal de transition tardive en présence d'un capteur de radicaux libres, afin d'obtenir un polymère d'addition linéaire pour ainsi dire exempt de radicaux libres de la forme poly¬oléfine non polaire)-(oléfine polaire)|.

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