Composition and process for the controlled synthesis of...

C - Chemistry – Metallurgy – 08 – K

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C08K 5/32 (2006.01) C08F 4/00 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2534535

The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one hydroxylamine of high molecular weight, preferably a long chain alkyl substituted hydroxylamine. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of high molecular weight hydroxylamines for controlled polymerization.

L'invention décrit une composition polymérisable qui contient: a) au moins un monomère éthylénique insaturé, et b) au moins un hydroxylamine de poids moléculaire élevé, de préférence un hydroxylamine à substitution alkyle à longue chaîne. D'autres aspects de l'invention décrivent un procédé de polymérisation de monomères éthyléniques insaturés, ainsi que l'utilisation d'hydroxylamines de poids moléculaire élevé dans la polymérisation contrôlée.

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