Compositions and methods for enhancing hybridization...

C - Chemistry – Metallurgy – 12 – Q

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C12Q 1/68 (2006.01)

Patent

CA 2266847

Compositions and methods are provided for increasing the specificity of a probe nucleic acid for a target nucleic acid in a hybridization solution. An abasic residue, deoxyNebularine residue, or a hybotrope is used to increase specificity. A method is provided for identifying useful hybotropes, including salts, water miscible organic solvents, aprotic solvents and organic solvents, on the basis of enthalpy considerations. Hybotropic hybridization and modified oligonucleotides may be used in amplification reactions, such as PCR, sequence analysis methods, and genomic screening methods.

L'invention concerne des compositions et des procédés permettant d'augmenter la spécificité d'un acide nucléique d'une sonde pour un acide nucléique dans une solution d'hybridation. Un résidu abasique, un résidu de désoxyNébularine ou un hybotrope est utilisé pour augmenter la spécificité. L'invention porte sur un procédé d'identification d'hybotropes utiles, dont des sels, des solvants organiques miscibles avec l'eau, des solvants aprotiques et des solvants organiques, selon des critères d'enthalpie. L'hybridation hybotrope et des olignonucléotides modifiés peuvent être utilisés dans des réactions d'amplification, telles que la PCR, des méthodes de séquençage et de dosage génomiques.

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