Concentration of tritium hydroxide and/or di-tritium oxide...

C - Chemistry – Metallurgy – 25 – B

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204/78.4

C25B 1/00 (2006.01) C01B 4/00 (2006.01)

Patent

CA 1126685

ABSTRACT OF THE DISCLOSURE In the reprocessing of spent nuclear fuel radioactive tritium is formed among other by products. Elemental tritium and/ or tritium hydride can be stored without control provided that the generated heat is dissipated. To concentrated and separate tritium and/or tritium hydride, the tritium water obtained in the reprocessing of spent nuclear fuel is enriched with tritium hydroxide and di-tritium oxide, for example by distillation and the mixture obtained is subjected to electrolysis, to convert tritium hydroxide and di-tritium oxide into tritium and/or tritium hydride. Conversion of the tritium in the tritium water into either elemental tritium or tritium hydride overcomes the storage problems encountered with tritium water.

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