Condensation polymer containing the residue of an...

C - Chemistry – Metallurgy – 08 – G

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402/194

C08G 63/52 (2006.01) C08G 63/54 (2006.01) C08G 63/68 (2006.01) C08G 64/04 (2006.01) C08K 5/00 (2006.01)

Patent

CA 1334465

Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or poly- carbonate (a) containing a mono-4-acyloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acyloxystyryl or bis-4- acyloxystyryl compound, having the formula or Image Image wherein each R1 is independently selected from cyano, carboxy, alkenyloxycarbonyl, or a substituted or unsubstituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each R2 is independently selected from one of the groups specified for R1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, aryl- sulfonyl or aromatic, carbocyclic or heterocyclic radical; each R3 is independently selected from hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; A1 and A2 are independently selected from 1,4-phenylene radicals; and R4 is an unsubstituted or substituted organic acyl radical and R5 is carbonyl, dicarbonyl or an unsubstituted or substituted organic diacyl radical. Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non- extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

591338

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