Continuous dosing of extremely fast initiators during...

C - Chemistry – Metallurgy – 08 – F

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C08F 14/06 (2006.01) C08F 4/32 (2006.01) C08F 4/38 (2006.01)

Patent

CA 2470839

The invention pertains to a process wherein initiators having a half-life from 0.0001 hour to 0.05 hour at the polymerization temperature are dosed to a polymerization mixture. The dosing of such initiator allows improved control of the polymerization rate and faster polymerization rates, and the process will render a polymer with very low residual initiator levels.

Cette invention se rapporte à un procédé grâce auquel des initiateurs ayant une demi-vie comprise entre 0,0001 heure et 0,05 heure à la température de polymérisation peuvent être dosés dans un mélange de polymérisation. Le dosage de ces initiateurs permet une régulation améliorée de la vitesse de polymérisation et des vitesses de polymérisation supérieures, et ce procédé permet d'obtenir des polymères ayant des niveaux très bas d'initiateurs résiduels.

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