Continuous process for preparing aluminum alkyls and linear...

C - Chemistry – Metallurgy – 07 – F

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C07F 5/06 (2006.01) C07C 1/32 (2006.01) C07C 5/25 (2006.01) C07C 11/02 (2006.01)

Patent

CA 2074231

Linear 1-olefins are continuously prepared from internal olefins by (i) continuously feeding internal olefin, isomerization catalyst and tri-lower alkyl aluminum to a reaction zone so as to cause the internal olefin to isomerize to 1-olefins which displace the lower alkyl groups to form a trialkyl aluminum compound in which at least one of the alkyl groups is a linear alkyl derived from the 1-olefin, (ii) continuously removing trialkylaluminum compound from the reaction zone and, thereafter, (iii) reacting the trialkyl aluminum compound with a 1-olefin so as to displace the linear alkyl from the trialkyl aluminum compound, thereby forming a linear 1-olefin product which is substantially free of internal olefins.

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