Continuous process for preparing poly(butylene...

C - Chemistry – Metallurgy – 07 – C

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C07C 67/02 (2006.01) C07C 69/80 (2006.01) C08G 63/78 (2006.01)

Patent

CA 2047994

Economic and efficient process for preparing an oligomer of poly(butylene terephthalate) or an oligomer of poly(butylene isophthalate) Pram a transesterification reaction mass by using a countercurrent column reactor system wherein the transesterification reaction mass is fed into the countercurrent column reactor and continuously flows downward while simultaneously a heated inert gas stream continuously flows upward to scrub out volatiles from the transesterification reaction mass, thereby yielding from the bottom of the countercurrent column reactor an oligomer of poly(butylene terephthalate) or an oligomer of poly(butylene isophthalate) suitable for use in a polycondensation reaction. Butanediol is recycled throughout the process through an absorber column.

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