Continuous process for the production of aldehydes by...

C - Chemistry – Metallurgy – 07 – C

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260/573.2

C07C 45/50 (2006.01) C07C 47/02 (2006.01) C07F 9/6574 (2006.01)

Patent

CA 1225660

ABSTRACT A continuous hydroformylation process for the production of an aldehyde by hydroformylation of an olefin comprises: providing a hydroformylation zone containing a charge of a liquid reaction medium having dissolved therein (a) a complex rhodium hydroformylation catalyst comprising rhodium in complex combination with carbon monoxide and with a cyclic phosphite having a phosphorus atom linked to three oxygen atoms at least two of which form together with the phosphorus atom part of a ring and (b) a ligand stabilising amount of tertiary amine; supplying said olefin to the hydroformylation zone; maintaining temperature and pressure conditions in the hydroformylation zone conducive to hydroformylation of the olefin; supplying make-up hydrogen and carbon monoxide to the hydroformylation zone; and recovering from the liquid hydroformylation medium a hydroformylation product comprising at least one aldehyde.

469950

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