Controlling premature curing of vulcanizable...

C - Chemistry – Metallurgy – 08 – K

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C08K 5/47 (2006.01) C08K 5/00 (2006.01) C08K 5/05 (2006.01) C08K 5/053 (2006.01) C08K 5/46 (2006.01) C08K 9/12 (2006.01) C08L 101/04 (2006.01)

Patent

CA 2138003

A process of reducing the effects of moisture during storage prior to vulcanization of a vulcanizable halogen-containing polymer composition containing water, comprising blending before storage, into said vulcanizable composition, a thioester derivative of 2,5-dimercapto-1,3,4-thiadiazole crosslinking agent and glycerin, whereby the scorch time of the vulcanizable compound is not significantly affected by the water content of said composition. In addition, a vulcanizable halogen-containing polymer composition comprising a thioester derivative of the crosslinking agent and glycerin, and a dry pourable powder cure premix composition comprising the crosslinking agent, glycerin and a pourable siliceous finely divided filler.

Méthode pour réduire les effets de l'humidité pendant le stockage, avant la vulcanisation d'une composition polymérique halogénée vulcanisable, renfermant de l'eau; la méthode consiste à mélanger avec ladite composition vulcanisable, avant le stockage, un dérivé thioester d'un réticulant à base de 2,5-dimercapto-1,3,4-thiadiazole, et de la glycérine; le temps de durcissement du composé vulcanisable n'est pas modifié sensiblement par la teneur en eau de ladite composition. De plus, l'invention porte sur une composition polymérique halogénée vulcanisable renfermant un dérivé thioester du réticulant et de la glycérine, ainsi que sur une composition-prémélange en poudre sèche coulable pour réticulation, renfermant le réticulant, la glycérine et une charge siliceuse finement divisée.

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