Convergent synthesis for kahalalide compounds

Details Convergent synthesis for kahalalide compounds Convergent synthesis for kahalalide compounds

C - Chemistry, Metallurgy

07

K

C07K 7/08 (2006.01) C07K 1/107 (2006.01)

Patent

CA 2563463

New synthetic routes to kahalalide compounds are provided. These are based on convergent approaches using orthogonal protecting schemes, where a better control of the intermediates is taken. Kahalalide F or a mimic of kahalalide F is synthesised by coupling a cyclic part with a side chain fragment, e.g. according to the reaction (1)

L'invention concerne de nouvelles voies de synthèse pour des composés kahalalide, lesquelles se basent sur des approches convergentes au moyen de structures de protection orthogonales où les intermédiaires sont mieux contrôlés. Selon l'invention, un kahalalide F ou un élément mimant le kahalalide F est synthétisé par couplage d'une partie cyclique avec un fragment de chaîne latérale, par exemple, en fonction de la réaction suivante (1).

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