C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
23/400, 260/648
C07C 41/06 (2006.01) B01J 8/04 (2006.01) C07C 43/04 (2006.01) C10G 3/00 (2006.01) C10L 1/02 (2006.01)
Patent
CA 2031184
F-5342 CONVERSION OF ALCOHOLS TO ETHER-RICH GASOLINE ABSTRACT Methanol or other alcohol is converted to high octane gasoline components by an integrated process wherein crude aqueous alcohol feedstock is extracted with a liquid extractant stream containing C4+ iso-olefin and reacted to form tertiary-alkyl ethers, such as MTBE. The aqueous raffinate is converted to olefinic hydrocarbons in a MTO catalytic reactor. Propene from the MTO reaction is reacted with water to produce di-isopropyl ether, which may be blended with MTBE and C6+ MTO hydrocarbons to produce high octane gasoline. Isobutylene and isoamylenes from the MTO reaction can be recovered and recycled as a liquid extractant stream.
Harandi Mohsen N.
Owen Hartley
Kirby Eades Gale Baker
Mobil Oil Corporation
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