Conversion of alcohols to ether-rich gasoline

C - Chemistry – Metallurgy – 07 – C

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23/400, 260/648

C07C 41/06 (2006.01) B01J 8/04 (2006.01) C07C 43/04 (2006.01) C10G 3/00 (2006.01) C10L 1/02 (2006.01)

Patent

CA 2031184

F-5342 CONVERSION OF ALCOHOLS TO ETHER-RICH GASOLINE ABSTRACT Methanol or other alcohol is converted to high octane gasoline components by an integrated process wherein crude aqueous alcohol feedstock is extracted with a liquid extractant stream containing C4+ iso-olefin and reacted to form tertiary-alkyl ethers, such as MTBE. The aqueous raffinate is converted to olefinic hydrocarbons in a MTO catalytic reactor. Propene from the MTO reaction is reacted with water to produce di-isopropyl ether, which may be blended with MTBE and C6+ MTO hydrocarbons to produce high octane gasoline. Isobutylene and isoamylenes from the MTO reaction can be recovered and recycled as a liquid extractant stream.

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