Conversion of aldose to ketose in the presence of a...

C - Chemistry – Metallurgy – 12 – P

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C12P 1/00 (2006.01) C07H 3/02 (2006.01) C07H 11/04 (2006.01) C12P 19/24 (2006.01) C13K 11/00 (2006.01)

Patent

CA 1067437

ABSTRACT OF THE DISCLOSURE A process for converting aldoses or dorivatives thereof into ketoses or derivatives thereof which takes place in the presence of oxyanions or mixed complex oxyanions of germanium or tin which form stronger complexes with the ketoses or derivatives thereof than with the aldoses or derivatives thereof. Using the process the equilibrium position in the aldose-ketose reaction is shifted towards higher proportions of ketose. The process is very applicable to the conversion of glucose to fructose particularly when this conversion takes place enzymatically in the presence of glucose isomers.

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