Conversion of alkanes to unsaturated aldehydes

C - Chemistry – Metallurgy – 07 – C

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C07C 47/22 (2006.01) B01J 27/192 (2006.01) B01J 27/199 (2006.01) C07C 5/333 (2006.01) C07C 45/33 (2006.01) C07C 45/35 (2006.01) C07C 45/37 (2006.01) C07C 51/25 (2006.01)

Patent

CA 1217502

TITLE CONVERSION OF ALKANES TO UNSATURATED ALDEHYDES INVENTOR SARGIS KHOOBIAR ABSTRACT Alkanes, particularly propane and isobutane are converted to unsaturated aldehydes, particularly acrolein and methacrolein in an integrated two-step process wherein the alkane is dehydrogenated in a first step to the corresponding olefin, hydrogen, and by-products and the reaction effluent is passed directly into a second step where the olefin is oxidized to the corresponding unsaturated aldehyde without significant oxidation of the hydrogen and by-products. The aldehydes and by-products may be separated and the unreacted olefin and alkane recycled to the first step. Alternatively, the effluent from the second step may be used as feed to a further oxidation step for conversion of the unsaturated aldehyde to the corresponding unsaturated acid.

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