Conversion of carbon dioxide to methanol using bi-reforming...

C - Chemistry – Metallurgy – 01 – B

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C01B 3/38 (2006.01) C01B 3/40 (2006.01) C07C 29/151 (2006.01) C07C 29/154 (2006.01) C07C 31/04 (2006.01)

Patent

CA 2690836

The invention provides for \ a method of forming methanol by combining a mixture of methane, water and carbon dioxide under reaction conditions sufficient to form a mixture of hydrogen and carbon monoxide. Hydrogen and carbon monox-ide are reacted under conditions sufficient to form methanol. The molar ratio of hydrogen to carbon monoxide is at least two moles of hydrogen to one mole of carbon monoxide and the overall molar ratio between methane, water and carbon dioxide is about 3:2:1. Methane, carbon dioxide and water are bi-reformed over a catalyst. The catalyst includes a single metal, a metal oxide, a mixed catalyst of a metal and a metal oxide or a mixed catalyst of at least two metal oxides.

L'invention concerne un procédé de formage de méthanol consistant à combiner un mélange de méthane, d'eau et de dioxyde de carbone dans des conditions réactionnelles suffisantes pour former un mélange d'hydrogène et de monoxyde de carbone. L'hydrogène et le monoxyde de carbone réagissent dans des conditions suffisantes pour former du méthanol. Le rapport molaire hydrogène sur monoxyde de carbone est d'au moins deux moles d'hydrogène pour une mole de monoxyde de carbone et le rapport molaire total entre le méthane, l'eau et le dioxyde de carbone est de 3:2:1 environ. Le méthane, le dioxyde de carbone et l'eau sont bi-formés grâce à un catalyseur. Ce catalyseur comprend un métal unique, un oxyde métallique, et un catalyseur mixte constitué d'un métal et d'un oxyde métallique ou un catalyseur mixte comprenant au moins deux oxydes métalliques.

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