Conversion of synthesis gas to lower olefins using modified...

C - Chemistry – Metallurgy – 10 – G

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C10G 2/00 (2006.01) B01J 29/06 (2006.01) B01J 37/02 (2006.01) B01J 37/08 (2006.01) C07C 1/04 (2006.01) C07C 1/12 (2006.01) B01J 29/85 (2006.01)

Patent

CA 2289993

The present invention provides a method for incorporating one or more Fischer Tropsch catalysts into molecular sieves comprising contacting untreated molecular sieves with a catalyst precursor in an inert atmosphere under first conditions effective to form complexes comprising said catalyst precursor and said molecular sieves; and, exposing said complexes to an inert atmosphere and to second conditions effective to dissociate volatile components from said catalyst precursor and to evaporate solvent from said complexes, forming modified molecular sieves comprising a catalytically effective amount of a catalyst selected from the group consisting of iron, cobalt, nickel, chromium, manganese, and rhodium.

Cette invention concerne un procédé permettant d'incorporer un ou plusieurs catalyseurs Fischer Tropsch dans des tamis moléculaires. Le procédé consiste à mettre en contact des tamis moléculaires non traités avec un précurseur de catalyseur dans une atmosphère inerte dans des premières conditions efficaces pour former des complexes comprenant ledit précurseur de catalyseur et lesdits tamis moléculaires; puis à exposer lesdits complexes à une atmosphère inerte et à des deuxièmes conditions efficaces pour dissocier les constituants volatiles dudit précurseur de catalyseur et pour évaporer le solvant contenu dans lesdits complexes, ceci formant des tamis moléculaires modifiés comprenant une quantité efficace du point de vue catalytique d'un catalyseur sélectionné dans le groupe formé par fer, cobalt, nickel, chrome, manganèse et rhodium.

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