Copolymers of ethylene with .alpha.-olefins

C - Chemistry – Metallurgy – 08 – F

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C08F 210/16 (2006.01) C08F 4/6192 (2006.01) C08F 4/69 (2006.01) C08L 23/08 (2006.01)

Patent

CA 2510061

Copolymers of ethylene with .alpha.-olefins which have a molar mass distribution Mw/Mn of from 1 to 8, a density of from 0.85 to 0.94 g/cm3, a molar mass Mnof from 10.000 g/mol to 4 000 000 g/mol and a CDBI of less than 50% and in which the side chain branching of the maxima of the individual peaks of the short chain branching distribution is in each case greater than 5 CH3/1 000 carbon atoms, a process for preparing them, a catalyst suitable for preparing them and fibers, moldings, films or polymer mixtures in which these copolymers are present.

L'invention concerne des copolymères d'éthylène contenant .alpha.-oléfines qui présentent une répartition M¿w?/M¿n? de masse molaire comprise entre 1 et 8, une densité comprise entre 0.85 et 0.94 g/cm?3¿, une masse molaire M¿n? comprise entre 10 000 g/mol et 4 000 000 g/mol et un indice d'ampleur de répartition de la composition (CDBI) inférieur à 50 % et dans lesquels la ramification de chaînes latérales du maximum des sommets individuels de la répartition des ramifications de chaînes courtes est, à chaque fois, supérieure à 5 CH¿3?/1 000 atomes de carbone. L'invention concerne également un procédé de préparation desdits copolymères, un catalyseur permettant de les préparer et des fibres, des moulages, des films ou des mélanges polymères, dans lesquels lesdits copolymères sont présents.

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