Copper-catalyzed enantioselective allylic substitution...

Details Copper-catalyzed enantioselective allylic substitution... Copper-catalyzed enantioselective allylic substitution...

C - Chemistry, Metallurgy

07

F

C07F 17/02 (2006.01) C07B 53/00 (2006.01)

Patent

CA 2341860

An allylic compound is reacted with an organozinc compound Zn(R6)2 to eliminate a group (the leaving group) from the allylic compound and to add a group from the organozinc compound to it in the presence of a copper salt catalyst and a chiral organic ligand for the copper.

L'invention porte sur un composé allylique mis à réagir avec un composé organate-zinc Zn(R<6>)2 pour éliminer un groupe (le groupe partant) du composé allylique et y ajouter un groupe provenant du composé organate-zinc en présence d'un catalyseur de sel de cuivre et d'un ligand organique chiral destiné au cuivre.

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