Coupling of chloroperfluoroalkanes

C - Chemistry – Metallurgy – 07 – C

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260/656.2

C07C 19/08 (2006.01) C07C 17/26 (2006.01)

Patent

CA 1242460

ABSTRACT A process for the coupling of a chloro- perfluoroalkane having a -CFC12 moiety which comprises heating the alkane at a temperature of about 150 to 260°C in the presence of at least about 0.1 times the molar amount each of copper and zinc at a mole ratio of copper:zinc from about 2:1 to 1:2. The product is obtained in relatively high yield and conversion.

496026

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