Coupling of reinforcing fibres to resins in curable composites

C - Chemistry – Metallurgy – 08 – J

Patent

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C08J 5/06 (2006.01) C08J 5/08 (2006.01) C08K 7/02 (2006.01) C08K 9/04 (2006.01) C08K 9/06 (2006.01)

Patent

CA 2429226

A method for preparing a moulded composite comprises milling reinforcing fibres to a mean fibre length of less than 5 mm, treating the milled fibres with a coupling agent and suspending the dried fibres in a liquid resin which reacts with the coupling agent on the fibres. Preferred fibres include glass fibres and milled mica coated with calcined iron oxide. Preferred coupling agents are organosilanes and metal acrylates e.g. zinc diacrylate. Composites formed by the above method exhibit improved impact resistance, tensile strength and flexural strength.

L'invention concerne un procédé de préparation de composite moulé consistant à broyer des fibres de renforcement jusqu'à obtenir une longueur moyenne de fibre inférieure à 5 mm, à traiter les fibres broyées avec un agent de couplage et à suspendre les fibres séchées dans une résine liquide qui réagit avec l'agent de couplage placé sur les fibres. Les fibres sont, de préférence, des fibres de verre et de mica broyé recouvert d'oxyde de fer calciné. Les agents de couplage sont, de préférence, des organosilanes et des acrylates métalliques, par exemple du diacrylate de zinc. Les composites formés par le procédé de l'invention possèdent des résistances améliorées à l'impact, à la traction et à la flexion.

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