Cracking 1-ethers over unmodified .gamma.-alumina

Details Cracking 1-ethers over unmodified .gamma.-alumina Cracking 1-ethers over unmodified .gamma.-alumina

C - Chemistry, Metallurgy

07

C

C07C 1/20 (2006.01)

Patent

CA 2538206

1-Ethers may be cracked over untreated .gamma.-alumina having a pore volume of more than 1.0 cc/g and an average pore diameter of more than 150 angstroms (.ANG.) at a temperature from 250 to 350°C and a pressure from 10 to 200 kPa at high conversions and good selectivity to produce the corresponding 1-alkene. The process is particularly useful to produce 1-octene from 1-methoxyoctane.

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