Crosslinking agents for radiation crosslinking fluoropolymers

C - Chemistry – Metallurgy – 07 – C

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260/483, 400/641

C07C 69/533 (2006.01) C08F 259/08 (2006.01) C08K 5/10 (2006.01) C08K 5/103 (2006.01) C08K 5/20 (2006.01)

Patent

CA 1257873

ABSTRACT OF THE DISCLOSURE The present invention is a radiation sensitizer or crosslinking agent having the formula Image wherein n is from 2 to 6; R1 is selected from H and methyl radicals; R2 is a diradical selected from the group consisting of alkylene, cycloalkylene, aralkylene, and arylene diradicals having from 1 to 16 carbon atoms; and X is a polyfunctional radical wherein the functional groups are selected from -O-, Image , (where R is H or a (C1-C4) alkyl radical) and mixtures thereof, the radical having from 2 to 6 functional groups. The radiation sensitizer is useful in fluoropolymer compositions. The present invention also includes a method comprising the step of irradiating a fluoropolymer com- position. The composition can be melt processed followed by irradiation. The radiation sensitizer of the above composition is particularly stable during melt processing. Melt processing can include melt blending, such as extruder blending, and melt forming, such as wire coating.

476049

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