Crystalline mww-type titanosilicate, its preparation and use...

C - Chemistry – Metallurgy – 07 – C

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C07C 29/03 (2006.01) B01J 29/89 (2006.01) C07D 301/12 (2006.01) C07D 301/19 (2006.01) B01J 29/70 (2006.01)

Patent

CA 2423666

A crystalline titanosilicate catalyst which is usable as a catalyst in the oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group, a process for producing the catalyst, and a process for producing an oxidized compound by an oxidation reaction using the catalyst. It has been found that a crystalline titanosilicate having a structural code of MWW effectively functions as a catalyst in an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent, thereby to highly selectively provide an intended oxidized compound.

L'invention concerne un catalyseur au silicate de titane cristallin pouvant être utilisé comme catalyseur dans la réaction d'oxydation d'un composé présentant une double liaison carbone-carbone et au moins un autre groupe fonctionnel. L'invention concerne également un procédé produire ledit catalyseur et un procédé pour produire un composé oxydé au moyen dudit catalyseur. On a découvert qu'un silicate de titane cristallin présentant un code structural de MWW agit de manière efficace comme catalyseur dans une réaction d'oxydation d'un composé présentant une double liaison carbone-carbone et au moins un autre groupe fonctionnel. La double liaison carbone-carbone est oxydée au moyen d'un peroxyde utilisé comme agent oxydant, ce qui permet d'obtenir de manière extrêmement sélective un composé oxydé voulu.

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