Crystallizable thermoplastic resins and dendrimers with...

C - Chemistry – Metallurgy – 08 – L

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C08L 67/00 (2006.01) C08G 63/08 (2006.01) C08L 101/00 (2006.01)

Patent

CA 2526525

The strain-hardening characteristics and melt rheology of thermoplastic resins including crystallizable polyester resins are modified by blending with a dendrimeric modifier. Blends comprising PET resins and up to about 2 wt.% of a dendrimer have increased melt strengths and exhibit a reduction in strain- hardening parameter, reflected in a lower strain level at the onset of strain hardening. Blends further comprise PET resins and a component comprising a ratio of dendrimer modifier to purified terephthalic acid.

Aux fins de l'invention, on modifie les caractéristiques d'écrouissage et la rhéologie de fusion de résines thermoplastiques par mélange avec un modificateur dendrimétrique. Les mélanges renfermant des résines PTPE et jusqu'à environ 2 % de dendrimère, en poids, ont une résistance à la fusion améliorée et présentent une réduction de coefficient d'écrouissage, ce qui donne un niveau de contrainte inférieur au moment de l'écrouissage. En outre, ces mélanges renferment des résines PTPE et une composante avec un rapport modificateur dendrimétrique à acide téréphtalique purifié.

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