Crystals of non-natural-type stereoisomer salt of monatin...

C - Chemistry – Metallurgy – 07 – D

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C07D 209/20 (2006.01) A23L 1/226 (2006.01) A23L 1/236 (2006.01) A23L 2/60 (2006.01) C07C 229/36 (2006.01) C07D 209/08 (2006.01)

Patent

CA 2467285

Crystals of salt of a stereoisomer which is a non-natural type of monatin which are applicable as a sweet taste substance are newly provided. The crystals are stable, have a high degree of sweet taste (high sweetening potency) and are expected for use as a sweetener or an ingredient thereof and also as a component for giving sweet taste to beverage, food, etc. A sweetener using the above-mentioned crystals of the salt which is a novel sweet taste substance and a product such as beverage and food to which sweet taste is given are able to be provided. The stereoisomer salt includes salts of a (2S,4R) substance, a (2R,4R) substance and a (2R,4S) substance of monatin and the salt of a (2R,4R) substance of monatin is particularly preferred.

L'invention vise la production nouvelle de cristaux de sels stéréoisomères non naturels de monatine lesquels sont utilisables en tant qu'édulcorants. Etant donné qu'ils sont stables et présentent un degré élevé de sucrosité, ces cristaux sont donnés comme étant utiles en tant qu'édulcorants ou leur constituants, et en tant qu'agents destinés à conférer un goût sucré à des aliments et à des boissons. Il est également possible de produire, par exemple, des édulcorants et des aliments ainsi que des boissons sucrés à l'aide des cristaux de sels précités en tant que nouvelles substances édulcorantes. Ces sels stéréoisomères comprennent les sels isomères (2S, 4R), (2R, 4R) et (2R, 4S) de monatine. Parmi tous les sels, les sels isomères (2R, 4R) de monatine sont particulièrement favorables.

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