Curable resin composition, coating composition, coating...

C - Chemistry – Metallurgy – 08 – L

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C08L 33/14 (2006.01) C08L 83/04 (2006.01) C09D 133/06 (2006.01) C09D 133/14 (2006.01) C09D 183/04 (2006.01) C08L 33/06 (2006.01) C08L 83/06 (2006.01)

Patent

CA 2185680

The present invention provides a novel curable resin composition insuring good curability even without using an aminoplast curing agent and having an excellent high-solid feature, a sufficient storage stability which consists in a curable resin composition comprising 5 to 80 weight % of a polymer containing free and esterified carboxyl groups and having an acid value of 50 to 300 (mgKOH/g) (1e), 1 to 80 weight % of a polymer containing hydroxyl and epoxy groups and having an epoxy equivalent of 200 to 1000 and a hydroxyl equivalent of 250 to 1500 (2d), and 1 to 50 weight % of an alkoxyl group-containing silicone polymer having an alkoxyl equivalent of 50 to 1500 (3a), 0.1 to 5.0 weight % of a quartenary ammonium salt catalyst (4a) and 0.1 to 5.0 weight % of a monoalkyltin compound (5a).

Nouvelle composition de résine durcissable assurant un bon durcissement même en l'absence d'un agent de durcissement aminoplaste et présentant d'excellentes qualités de solidité et une excellente stabilité au stockage. Cette composition de résine renferme 5 à 80 % en poids d'un polymère contenant des groupes carboxyle libres et estérifiés et présentant un indice d'acidité de 50 à 300 (mgKOH/g) (1e), 1 à 80 % en poids d'un polymère renfermant des groupes hydroxyle et époxy et présentant un équivalent époxy de 200 à 1000 et un équivalent hydroxyle de 250 à 1500 (2d), et 1 à 50 % en poids d'un polymère de silicone renfermant un groupe alcoxyle, présentant un équivalent alcoxyle de 50 à 1500 (3a), 0,1 à 5 % en poids d'un catalyseur à sels d'ammonium quaternaire (4a) et 0,1 à 5 % en poids d'un composé de monoalkyltine (5a).

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