Cyano-and polycyanometalloporphyrins as catalysts for alkane...

Details Cyano-and polycyanometalloporphyrins as catalysts for alkane... Cyano-and polycyanometalloporphyrins as catalysts for alkane...

C - Chemistry, Metallurgy

07

C

C07C 29/50 (2006.01) B01J 31/18 (2006.01) C07C 31/02 (2006.01) C07C 35/02 (2006.01) C07C 45/33 (2006.01) C07C 45/34 (2006.01) C07D 487/22 (2006.01) C07F 1/08 (2006.01) C07F 11/00 (2006.01) C07F 13/00 (2006.01) C07F 15/00 (2006.01)

Patent

CA 2077980

ABSTRACT In one embodiment, alkanes are oxidized by contact with oxygen-containing gas in the presence as catalyst of a metalloporphyrin containing cyano groups on the porphyrin ring. The catalysts may contain, in addition to cyano groups, halogen atoms on the porphyrin ring. In another embodiment, new compositions of matter comprising cyano- substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

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