Deallylation reactive and deallylation process using said...

Details Deallylation reactive and deallylation process using said... Deallylation reactive and deallylation process using said...

C - Chemistry, Metallurgy

07

K

C07K 1/06 (2006.01) B01J 23/44 (2006.01) C07C 209/62 (2006.01) C07C 211/01 (2006.01) C07C 211/35 (2006.01) C07C 213/08 (2006.01) C07C 227/18 (2006.01) C07C 229/36 (2006.01) C07D 207/16 (2006.01) C07D 211/52 (2006.01) C07D 211/62 (2006.01) C07D 295/088 (2006.01) C07H 19/04 (2006.01) C07K 1/12 (2006.01) C07C 211/27 (2006.01) C07C 211/28 (2006.01) C07C 215/30 (2006.01) C07C 229/08 (2006.01)

Patent

CA 2160163

Reagent and method useful for splitting a protected function, in the event of organic synthesis by an allyl group with the latter. The reagent is characterized by having a) a solvent system; b) a catalyst comprising at least one element from column VIII of the periodic table of elements, said element being coordinated by at least one coordinating agent soluble in the said solvent system; and c) a compound at least partially soluble in said solvent system and carrying at least one nucleophilic function. Application in organic synthesis.

La présente invention a pour objet un réactif et un procédé utile pour cliver une fonction protégée, à l'occasion d'une synthèse organique par un groupe allyle, d'avec celui-là. Ce réactif se définit en ce qu'il comporte: a) un système de solvant(s); b) un catalyseur comportant au moins un élément de la colonne VIII de la classification périodique des éléments, ledit élément de la colonne VIII de la classification périodique étant coordiné par au moins un agent de coordination soluble dans ledit système de solvant(s); c) un composé soluble au moins partiellement dans ledit sytème de solvant(s) et portant au moins une fonction nucléophile. Application à la synthèse organique.

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