Degradation of halogenated carbon compounds

Details Degradation of halogenated carbon compounds Degradation of halogenated carbon compounds

C - Chemistry, Metallurgy

25

B

204/81, 260/663.

C25B 3/02 (2006.01) A62D 3/00 (2006.01)

Patent

CA 1180356

ABSTRACT OF THE DISCLOSURE Halogen carbon compounds containing at least three halogen atoms and capable of undergoing bimolecular nucleophilic substitution are degraded by reaction in an aprotic solvent with a strong nucleophile selected from superoxide ion and hydroxide ion. The process is particularly applicable to compounds in which at least three halogen atoms are covalently joined to a tetrahedral carbon atom. In a specified embodiment, superoxide ion is electrolytically generated in an aprotic solvent contain- ing a soluble organic electrolyte. In a further embodiment, the aprotic solvent is dimethyl sulfoxide, which, when converting carbon tetrahalide, forms dimethylsulfone and carbonate.

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