Dehydrogenation of alkyl aromatic hydrocarbons

B - Operations – Transporting – 01 – J

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252/1.D, 260/682

B01J 20/30 (2006.01) C07C 15/42 (2006.01)

Patent

CA 1046481

A B S T R A C T Method for activating self-regenerative catalysts used for dehydrogenating alkyl aromatic hydrocarbons at 600-700°C., having specified number of carbon atoms char- acterized by interrupting the feed of hydrocarbon, while continuing the feed of steam, for 7-30 minutes each 24-48 hours. Suitable catalysts are those having a major pro- portion of at least one oxide of iron, zinc, chromium, or magnesium and an alkali metal oxide, hydroxide or carbonate. By this method, conversion to the desired alkenyl derivatives is increased, selectivity remains high and the dehydrogenation can be run under high severity conditions without excessive coking of the catalyst.

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