Dendritic, nitrogen-containing organic compounds containing...

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 251/24 (2006.01) C07C 5/02 (2006.01) C07C 255/61 (2006.01) C07C 317/36 (2006.01) C07C 323/31 (2006.01) C07D 301/06 (2006.01) C07F 1/00 (2006.01) C07F 13/00 (2006.01) C07F 15/00 (2006.01) C08G 73/02 (2006.01) C08G 83/00 (2006.01)

Patent

CA 2207019

The present invention relates to dendritic, nitrogen-containing organic compounds containing at least 4 planar-chiral or axial-chiral groups, where these planar-chiral or axial-chiral groups are linked as Schiff's bases to the primary amino groups of compounds of the formula (I) (R1R1)N-X-N(R1R1) (I) where R1 is (R2R2)N-(CH2)2- or (R2R2)N-(CH2)3-, R2 is hydrogen or (R3R3)N-CH2)2- or (R3R3)N-(CH2)3-, R3 is hydrogen or (R4R4)N-(CH2)2- or (R4R4)N-(CH2)3-, R4 is hydrogen or (R5R5)-N-(CH2)2- or (R5R5)N-(CH2)3-, R5 is hydrogen or (R6R6)N-(CH2)2- or (R6R6)N-(CH2)3- and R6 is hydrogen, X is an aliphatic and/or aromatic group, which may contain heteroatoms, which are suitable as catalysts for asymmetrical homogeneous catalysis.

L'invention porte sur des composés organiques dentritiques, renfermant au moins 4 groupes chiraux planaires, ou chiraux axiaux; ces groupes sont liés comme bases de Schiff aux groupes amino primaires de composés de formule (I) (R1R1)N-X-N(R1R1) (I) où R1 est (R2R2)N-(CH2)2- ou (R2R2)N-(CH2)3-, R2 est de l'hydrogène ou (R3R3)N-CH2)2- ou (R3R3)N-(CH2)3-, R3 est de l'hydrogène ou (R4R4)N-(CH2)2- ou (R4R4)N-(CH2)3-, R4 est de l'hydrogène ou (R5R5)-N-(CH2)2- ou (R5R5)N-(CH2)3-, R5 est de l'hydrogène ou (R6R6)N-(CH2)2- ou (R6R6)N-(CH2)3- et R6 est de l'hydrogène, X est un groupe aliphatique et (ou) aromatique, qui peut contenir des hétéroatomes, utiles comme catalyseurs pour la catalyse homogène asymétrique.

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