Deprotection of allylic esters and ethers

Details Deprotection of allylic esters and ethers Deprotection of allylic esters and ethers

C - Chemistry, Metallurgy

07

D

260/106.1, 260/2

C07D 477/00 (2006.01) C07C 37/055 (2006.01) C07C 51/09 (2006.01) C07D 477/08 (2006.01) C07D 499/00 (2006.01)

Patent

CA 1273630

Abstract of the Disclosure A process is disclosed for the deprotection of allylic esters and ethers. The process comprises reacting an allyl ester of a carboxylic acid or an allyl ether of a phenol with pyrrolidine or piperidine and a catalytic amount of an organic-soluble palladium complex having a coordina- ting phosphine ligand to cleave the allyl moiety. The re- sultant carboxylic acid or phenol is then recovered.

506363

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