Desulfurization and novel sorbents for same

B - Operations – Transporting – 01 – J

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B01J 20/32 (2006.01) B01J 20/06 (2006.01)

Patent

CA 2387986

Particulate sorbent compositions which are suitable for the removal of sulfur from streams of cracked-gasoline or diesel fuel are provided which have increased porosity, improved resistance to deactivation through the addition of a calcium compound selected from the group consisting of calcium sulfate, calcium silicate, calcium phosphate or calcium aluminate to the support system comprised of zinc oxide, silica and alumina having thereon a promotor wherein the promotor is metal, metal oxide or metal oxide precursor with the metal being selected from the group consisting of cobalt, nickel, iron, manganese, copper, molybdenum, tungsten, silver, tin and vanadium or mixtures thereof and wherein the valence of such promotor has been substantially reduced to 2 or less. Process for the preparation of such sorbent systems as well as the use of same for the desulfurization of cracked-gasolines and diesel fuels are also provided.

L'invention concerne des compositions sorbantes conçues pour éliminer le soufre contenu dans des courants de carburants à essence ou diesel de craquage, qui présentent une porosité accrue, une meilleure résistance à la désactivation par l'adjonction d'un composé de calcium, choisi dans le groupe constitué de sulfate de calcium, de silicate de calcium, de phosphate de calcium ou d'aluminate de calcium, au système de support constitué d'oxyde de zinc, de silice et d'alumine revêtu d'un promoteur qui est un métal, un oxyde métallique ou un précurseur d'oxyde métallique, le métal étant choisi dans le groupe constitué de cobalt, de nickel, de fer, de manganèse, de cuivre, de molybdène, de tungstène, d'argent, d'étain et de vanadium ou de leurs mélanges et dans lequel la valence du promoteur a été sensiblement réduite à 2 ou moins. L'invention traite également de procédés de préparation de ces systèmes sorbants et de leur utilisation pour désulfurer des carburants à essence et diesel de craquage.

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