Desulphurisation of oil

C - Chemistry – Metallurgy – 10 – G

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C10G 45/04 (2006.01) C10G 27/04 (2006.01)

Patent

CA 2054070

Case 7656(2) ABSTRACT OF THE DISCLOSURE DESULPHURISATION OF OIL A process for desulphurising hydrocarbon oils comprises the steps of (1) treating a sulphur containing hydrocarbon oil with a catalyst consisting essentially of an aqueous acidic or neutral solution of a molybdenum, tungsten or vanadium heteropolyanion and an oxidant under conditions such that the sulphur is oxidised and (2) separating the oxidised sulphur from the treated hydrocarbon oil. Preferred catalysts include those heteropolyanions derivable by ionisation of an acid having the general formula He(XkMnOy) where X is selected from phosphorus, antimony, silicon, germanium or boron; M is selected from molybdenum, tungsten or vanadium; k is from 1 to 5; n is from 5 to 40; y is from 18 to 62 and e is the valance of the (XkMnOy)e- anion.

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