Detergent compositions containing modified alkylaryl...

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 309/31 (2006.01) C11D 1/22 (2006.01) C11D 1/83 (2006.01) C11D 1/86 (2006.01) C11D 1/94 (2006.01)

Patent

CA 2379394

The present invention is directed to detergent compositions, comprising aryl- alkane sulfonate produced by paraffin isometization followed by paraffin dehydrogenation, then by alkylation of an aryl compound by a lightly branched olefin, then by sulfonating, and finally optionally, neutralizing. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. These modified alkylbenzene sulfonates produced have improved cleaning effectiveness in hard and/or cold water while also biodegradability comparable to that of linear alkylbenzene sulfonates.

La présente invention porte sur des compositions détergentes comprenant un aryl-alkane sulfonate produit par isométisation de la paraffine, puis par déshydrogénation de celle-ci, et ensuite par alkylation d'un composé aryle par une oléfine légèrement ramifiée, et par sulfonation, et enfin, éventuellement, par neutralisation. L'effluent de la zone alkylation comprend des paraffines qui sont recyclées vers l'étape d'isomérisation ou vers l'étape de déshydrogénation. Ces sulfonates alkylbenzène modifiés obtenus ont une meilleure efficacité de nettoyage en eau dure et/ou froide et ont également une biodégradabilité comparable à celle de sulfonates alkylbenzène linéaires.

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