Diglyceride manufacture

C - Chemistry – Metallurgy – 11 – C

Patent

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260/483.4, 260/4

C11C 3/02 (2006.01) C11C 3/06 (2006.01)

Patent

CA 1152097

Abstract Saturated triglycerides are reacted with glycerol in the presence of either a glycerolysis catalyst or a pre-formed glycerate to provide a product which is a mixture of monoglycerides, triglycerides, 1,2-diglycerides and 1,3-diglycerides. The mixture is stored in the presence of a low temperature rearrangement catalyst at a storage temperature below the melting point of the glyc- eride ester components of the mixture and substantially all of the mixture is converted into 1,3-diglycerides. In this way there are prepared, for example, 1-palmitoyl,3- stearoyl diglyceride, 1,3-distearoyl diglyceride and 1,3- dipalmitoyl diglyceride, which are appropriate precursors for the synthesis of confectioner's hard butters, and the like.

337947

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