Dimeric carbonylation of 1,3-butadiene

Details Dimeric carbonylation of 1,3-butadiene Dimeric carbonylation of 1,3-butadiene

C - Chemistry, Metallurgy

07

C

260/485.3, 260/4

C07C 69/657 (2006.01) C07C 69/587 (2006.01)

Patent

CA 1148171

ABSTRACT OF THE DISCLOSURE This invention involves a process for dimeric carbonylation of 1,3- butadiene in the presence of an alkanol and a palladium-phosphine complex catalyst to yield alkyl nonadienoate. An important aspect of the invention process is the recovery of a separate alkanol-rich liquid phase which con- tains the catalyst in a highly reactive form suitable for recycle.

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