Dinaphtazepinium salts useful as enantioselective...

C - Chemistry – Metallurgy – 07 – D

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C07D 223/14 (2006.01) C07B 53/00 (2006.01) C07D 301/03 (2006.01) C07D 301/12 (2006.01) C07D 303/06 (2006.01) C07F 7/10 (2006.01)

Patent

CA 2228902

A compound of formula (Ia) or (Ib), wherein A and B each independently represents hydrogen or one, two or three naphthylidene substituents, which substituents are selected from C1-6 alkyl, C1-6 alkoxy, aryl, aryloxy, silyl and silyloxy; R1 represents phenyl, C1-6 alkyl, phenyl C1-6 alkyl or a moiety of formula (a): wherein R2 represents C1-6 alkyl, phenyl or benzyl, R3 represents H or OR4 wherein R4 is C1-6 alkyl or C1-6 alkylsilyl and n is zero or an integer 1 or 2; and X is a counter ion; a process for the preparation of such compounds and the use of such compounds for enantioselectively epoxidising a prochiral olefin.

Composé répondant à la formule (Ia) ou (Ib), dans laquelle A et B représentent chacun indépendamment hydrogène ou un, deux ou trois substituants naphtylidène choisis parmi alkyle C¿1-6?, alcoxy C¿1-6?, aryle, aryloxy, silyle et silyloxy; R?1¿ représente phényle, alkyl C¿1-6?, phénylalkyle C¿1-6?, ou une fraction de formule (a) dans laquelle R?2¿ représente alkyle C¿1-6?, phényle ou benzyle, R?3¿ représente H ou OR?4¿, R?4¿ représentant alkyle C¿1-6? ou alkylsilyle C¿1-6?, et n vaut zéro ou un nombre entier choisi entre 1 et 2; et X représente un contre-ion; procédé de préparation de tels composés, et leur utilisation pour époxyder de façon énatiosélective une oléfine prochirale.

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