Dinitrobenzophenone solution and process for preparing an...

C - Chemistry – Metallurgy – 08 – L

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400/112, 402/220

C08L 77/10 (2006.01) C08G 73/10 (2006.01) C08L 61/00 (2006.01)

Patent

CA 1253882

NOVEL DINITROBENZOPHENONE SOLUTION AND PROCESS FOR PREPARING AN ETHER SOLUTION OF DIAMINOBENZOPHENONES THEREFROM Abstract of the Disclosure A novel ether solution of dinitrobenzophenone and a process for preparing an ether solution of diaminobenzophenone therefrom which comprises subjecting a dinitrobenzophenone dissolved in said ether solvent to hydrogenation in contact with a continuous nickel catalyst to obtain said solution of diaminobenzophenone dissolved in said ether solvent. In a specific embodi- ment said nickel catalyst is mounted on an inert support. In a still further embodiment, said diaminobenzophenone dissolved in said ether solvent, after removal of water therefrom, is reacted with an aromatic dianhydride to obtain a polyamic acid solution. The polyamic acid solution can be heated at a temperature above 100°C. to drive off water of cyclization and thereby obtain the corresponding polyimide resin.

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