Diorganopolysiloxane-azobenzene alternating copolymers and...

C - Chemistry – Metallurgy – 08 – G

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402/21

C08G 77/42 (2006.01) C08G 77/54 (2006.01)

Patent

CA 1298930

ABSTRACT Novel diorganopolysiloxane-azobenzene alternating copolymers composed of repeat units having the formula Image (1) wherein n has a value greater than or equal to 1; each R1 is independently selected from a group consisting of a hydrogen atom, a monovalent hydrocarbon group and an alkoxy group; each R2 is independently selected from a group consisting of a monovalent hydrocarbon group and an alkoxy group; each R3 is a linking group selected from a group consisting of an oxygen atom, C2-C6 alkylene groups, -O(C=O)-, -R4-N(R5)-(C=O)-, and -R6-(C=O)-N(R7)-, are described. These copolymers undergo reversible photo- mediated changes in their viscosity and absorption spectra. Also described are methods for preparing these novel copolymers.

557963

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