Direct fluorination process for making perfluorinated...

C - Chemistry – Metallurgy – 07 – C

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C07C 43/313 (2006.01) C07B 39/00 (2006.01) C07C 41/48 (2006.01) C07C 51/363 (2006.01) C07C 53/21 (2006.01) C07C 69/63 (2006.01) C07D 313/04 (2006.01)

Patent

CA 2004471

A liquid phase process for making perfluorinated organic substances which comprises directly contacting in a temperature-controlled reactor a diluted solution or dispersion of a perfluorinateable, organic substance in a liquid, inert medium with a stoichiometric excess of fluorine gas, optionally diluted with an inert gas, to perfluorinate said organic substance at a temperature and a flow rate of inert gas (if used) sufficient to volatilize the resulting by-product hydrogen fluoride, removing said hydrogen fluoride from the reactor as it is produced, and separately removing from the reactor the resultant solution or dispersion of perfluorinated organic substance.

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