Direct synthesis by living cationic polymerization of...

C - Chemistry – Metallurgy – 07 – C

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C07C 247/10 (2006.01) C08F 2/38 (2006.01) C08F 4/00 (2006.01) C08F 8/00 (2006.01) C08F 8/30 (2006.01) C10M 177/00 (2006.01)

Patent

CA 2111313

- 193 - Abstract A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen- containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or_ thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

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