Disposal of arsenic from sulfur dioxide-containing solutions

C - Chemistry – Metallurgy – 02 – F

Patent

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C02F 1/62 (2006.01) C22B 3/44 (2006.01) C22B 30/04 (2006.01)

Patent

CA 2255874

The process provides a method of removing arsenic from solutions containing sulfur dioxide in an environmentally acceptable manner. This process first oxidizes arsenic, iron and sulfur dioxide contained in an aqueous solution to prepare the solution for precipitation and to improve process control. Recycled neutralized precipitate seeds the oxidized aqueous solution. A calcium-containing base precipitates products of neutralization on the seeds. The final neutralized precipitate contains a stable ferric arsenate compounds.

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