Dithioacid rhenium sulfide dimer compositions

Details Dithioacid rhenium sulfide dimer compositions Dithioacid rhenium sulfide dimer compositions

C - Chemistry, Metallurgy

07

F

260/428.1, 260/2

C07F 13/00 (2006.01)

Patent

CA 1315785

ABSTRACT OF THE DISCLOSURE Briefly stated, the present invention encompasses a new class of rhenium 1,1-dithioacid complexes and their method of preparation. The complexes have the general formula [L2Re(µ-S)]2 wherein L is a dithioacid or similar ligand, and denotes the fact that the sulfur atoms in the core of the complex bridge the two rhenium atoms in the complex. Thus, the core structure for such typical compounds is generally of the form: Image where the dangling valences are associated with the sulfur atoms of a 1,1-dithioacid, L.

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