Divalent metal salts of dodecametal triaconta carbonyls

Details Divalent metal salts of dodecametal triaconta carbonyls Divalent metal salts of dodecametal triaconta carbonyls

C - Chemistry, Metallurgy

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C01G 55/00 (2006.01) B01J 31/20 (2006.01) C01G 1/04 (2006.01) C07C 29/156 (2006.01) C07C 29/157 (2006.01) C07C 29/158 (2006.01) C07C 31/00 (2006.01)

Patent

CA 1045337

DIVALENT METAL SALTS OF ABSTRACT OF THE INVENTION This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula: M[TyT'12-y (CO)30] wherein M is a divalent metal cation which is one of beryllium, magnesium, calcium, strontium, radium, scandium, yttrium, manganese, iron, ruthenium, rhenium, cobalt, nickel, palladium, platinum, zinc, cadmium, mercury, cerium and europium, T and T' are each different metals selected from the group consisting of cobalt, iridium and rhodium, and y may be any whole number between 1 and 11. These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol. S P E C I F I C A T I O N -1-

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