Double salt, process for its preparation and pharmaceutical...

C - Chemistry – Metallurgy – 07 – H

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C07H 5/04 (2006.01) A61K 31/70 (2006.01) C07D 233/88 (2006.01) C07H 15/26 (2006.01)

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CA 1238318

ABSTRACT Double salt, process for its preparation and pharmaceutical composition containing it. The double sulfate of 1-desoxy-(5-hydroxytryptamino)- D-fructose (DFS) and 1-methylhydantoin-2-imide (creatinine) represents a new solid crystalline phase of unit composition, pharmaceutical quality and remarkable stability. It is prepared by glycosylation of serotonin with D- glucose, formation of the double salt by addition of sulfuric acid and creatinine and crystallization of the double salt in the presence of ethanol. The DFS is preferably isolated from the reaction medium by way of the addition complex DFS.Ca(OH)2 which is precipitated by the addition of calcium hydroxide. The calcium hydroxide is then eliminated by addition of sulfuric acid and the double salt crystallized as described above. The DFS is the active principle of a medicament effective in particular in the treatment of leprosy.

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